Hardness
The hardness of ceramic materials is a property which
is of high significance as it relates to the ability of the
material to withstand penetration of the surface through a combination
of brittle fracture and plastic flow.
Often, hardness is directly equated to wear resistance. This
is a mistaken concept with many metallic components and is definitely
an incorrect selection criterion with regards to engineering
ceramic materials.
Wear behaviour of ceramic materials is complex and is dependent
upon many variables, of which hardness is an important variable
but not the only significant variable.
For example, in many wear environments, such as the erosive
wear behaviour of oxide engineering ceramics, it is the ratio
of fracture toughness to hardness which is found to be of most
significance in determining the wear performance.
In many wear environments, a much “softer” material
such as a zirconia can outperform “harder” materials
such as aluminas or silicon carbide.
Hardness measurements in engineering ceramics are generally
measured using a Vickers hardness test. In this test a pyramidal
diamond indenter is pressed into a polished surface under known
loading conditions and the size of the indentation is related
to the hardness of the material.
It should also be noted that the hardness value quoted for
any material is a function of the type of test conducted and
the loading conditions employed. Lighter loads typically provide
higher hardness values.
Typically in a Vickers Hardness test, the notation HV10 or
HV20 relates to the applied load in Kg (in this case 10 or 20
kg respectively).
Other factors that need to be taken into account when interpreting
hardness data for ceramic materials are the amount of porosity
in the surface, the grain size of the microstructure and the
effects of grain boundary phases.
Some typical hardness values for ceramic materials are provided
below:
| Material Class |
Vickers Hardness (HV) GPa |
| Glasses |
5 – 10 |
| Zirconias, Aluminium Nitrides |
10 - 14 |
| Aluminas, Silicon Nitrides |
15 - 20 |
| Silicon Carbides, Boron Carbides |
20 - 30 |
| Cubic Boron Nitride CBN |
40 - 50 |
| Diamond |
60 – 70 > |
Please contact our sales engineers for further advice on the
hardness properties of our engineering ceramic materials and
how such properties may relate to your application.
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